Rui Qiao, PhD

Virginia Tech

Friday, January 13, 2023

9:30 AM

102 Benedum Hall

Host: Lei Li

Molecular Physics of Carbon Storage and Utilization in Tight Reservoirs

Abstract:

Oil from tight reservoirs has grown to dominate the liquid petroleum production in the U.S. This greatly benefited the petroleum industry, but it faces challenges in improving oil recovery from these reservoirs and reducing its carbon footprint. CO₂ injection for enhanced oil recovery (EOR) and CO₂ sequestration helps address these challenges. However, its practice is hindered by a lack of predictive tools for the storage and transport of oil and CO₂ in these reservoirs. Fundamentally, since tight reservoirs’ porosity is dominated by pores smaller than 10-100nm, confinement and chemistry of pore walls can affect the storage and transport of oil-CO₂ in these reservoirs, and physical processes underpin their effects occur at the molecular scale. Here, I will introduce our work on the molecular thermodynamics and hydrodynamics of CO₂ EOR and sequestration in tight reservoirs. I will first examine CO₂-mediated oil transport in nanopores, focusing on the dual role of interfacial CO₂ in modulating oil flow. Next, I will examine critical steps in the Huff-n-Puff scheme of EOR and CO₂ sequestration at the single nanopore scale, focusing on the transport and storage of CO₂ in nanopores, the recovery of oil from pores, and their coupling. Overall, our work highlights the critical role of adsorption in oil recovery and CO₂ storage in tight reservoirs. Dimensionless parameters governing the importance of adsorption are identified, and the scaling law of oil recovery in the presence of adsorption is revealed.

Bio: Dr. Rui Qiao received his B.S. degree from Huazhong University of Science and Technology and an M.S. degree from Tsinghua University. He obtained his Ph.D. and postdoctoral training at the University of Illinois at Urbana-Champaign. He was a faculty at Clemson University from 2005 to 2014 and joined Virginia Tech in 2014. He has worked on the molecular, continuum, and multiscale simulations of diverse problems, including nanofluidics, mass and heat transfer in porous media, shale gas extraction, and electrical energy storage. These works all center on clarifying the essential physics of interfacial and transport phenomena underlying advanced technologies to shape and accelerate their development.